Army Hazmat Course
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When you think of Resource conservation and recovery act (RCRA) THINK...
hazardous waste
OHSA
Occupational Health and Safety Act.. covered under 29 CFR 1910.120
EPA is covered by
40 CFR 300-311-
DOT is covered by
49 CFR 100-199-
NFPA 472
Competence for responders to Hazardous Material
NFPA 473
Competence for EMS personnel
What is an Awareness Level Responder
They are expected to recognize, protect themselves, call for trained personnel, secure the area, evacuate, and deny entry
While analyzing an incident the goal is to...
Detect, survey, collect, and implement actions consistent with AHJ (Authority having jurisdiction)
Isolation
set perimeters and zones using the ERG. Deny entry to the contaminated area and assist with evacuate
Protection
initiate the incident command system, ensuring the protection of responders and the public
Hazardous Materials defined by NFPA 472
A substance (either matter-solid, liquid, or gas- or energy) that when released causes harm to PEOPLE, ENVIRONMENT, and, PROPERTY
DOT uses hazardous materials
to cover the 9 hazard classes
EPA uses hazardous substances
that if released into the environment above a certain amount, it must be reported
EPA uses extremely hazardous substances
for chemicals that must be reported if released above a THRESHOLD
Toxic Chemicals
chemicals whose total emissions or release be reported Annually by owners that manufacture, process, or otherwise use a listed toxic chemicals
OHSA uses hazardous chemicals
to denote any chemical that would be a risk to employees in the workplace
Dangerous goods
In united nations model codes and regulations, hazardous materials are known as
OHSA uses Highly hazardous chemicals
chemicals that possess toxic, reactive, flammable, or explosive property
Weapons of Mass Destruction
Any weapon involving toxic or poisonous chemicals, disease organism, or designed to release radiation
Class 1 major hazard
Class 1 : Explosives Major hazard: Explosion
Division 1.1
Mass explosion hazard ex: Dynamite, T-N-T
Division 1.2
Projection Hazard ex: Detonation Cord
Division 1.3
Fire Hazard ex: Liquid- fueled rocket motors
Division 1.4
Minor explosion hazard ex: ammunition
Division 1.5
very insensitive explosives ex: Prilled ammunition nitrate fertilizer
Division 1.6
extremely insensitive articles ex: Firecracker
Class 2 major hazards sub-hazards
Class 2: gases major hazards: BLEVE (Boiling liquid expanding vapor explosion Sub-hazards: Flammable, oxidizer, and poisonous
Division 2.1
Flammable gas ex: Propane
Division 2.2
Non-flammable, non- poisonous ex: compressed OXYGEN A cryogenic liquid
Division 2.3
Poisonous Gas ex: Chlorine
Class 3 Major Hazard
Class 3: Flammable and Combustible Liquids Major Hazard: Burns readily
Flammable liquid
Flash point of not more than 140 degrees F ex: acetone, amyl acetate, methyl alcohol, toluene, gasoline
Combustible Liquid
Flash point above 140 degrees F and below 200 degrees F ex: mineral oil, fuel oil, peanut oil
Class 4 Major Hazard
Class 4: Flammable and Combustible Major hazard: Rapid Combustion with a liberation of mass quantities of smoke
Division 4.1
Flammable Solid DENSITIZED EXPLOSIVES( to suppress explosion) SELF- REACTIVE MATERIALS READILY COMBUSTIBLE SOLIDS ex: magnesium (pellets, turnings, and ribbons), Nitrocellulose
Division 4.2
Spontaneously combustible material PYROPHORIC MATERIAL SELF-HEATING MATERIAL ex: phorphorus
Pyrophoric Material
A liquid or solid that , even in small quantities and without an external ignition source, can ignite within five minutes after coming in contact with air
Division 4.3
Dangerous when wet "MRE heaters" calcium carbide magnesium powder
Class 5.1 Major Hazard
Supports combustion, intensifies fire ex: ammonium nitrate
Class 5.2 Major Hazard
Unstable/ reactive explosives ex: Methyl ethyl ketone peroxide
class 5
Oxidizers
Division 5.2 Type A-G
Type A: forbidden for transport Type B: Can undergo thermal explosion Type C: Cant undergo thermal explo. Type D. medium to no effect when heated under confinement Type E: low to no effect when heated Type F: low or no explosive powe Type G: Desensitized
Class 6
Poison major hazard: toxicity, infectious
Division 6.1
Poisonous material, other than a gas can cause irritation. "CS"
Division 6.2
Infectious substance, contain pathogens and cause disease in humans or animals ex: anthrax, botulism
Class 7
Radioactive Major Hazard: Radioactive poisonous burns ex: uranium 0.002 mircocuries/gram yellowcake
Class 8
Corrosive Major Hazard: Burns/Emulsification skin damage ex: sulfuric acid and nitric acid
Class 9
Miscellaneous A material that presents a hazard during transport, but is not included in another hazard class
ORM-D other regulated materials
Labels for materials that present a limited hazard during transport due to its form, quantity and packaging ex: consumer commodities " furniture polish/ fingernail polish"
Incidents Involving WMDs may have additional differences including
INTENT- inflict harm, and kill SEVERITY AND COMPLEXITY - large number of causalities CRIME SCENE MANAGEMENT-preservation of evidence INCIDENT COMMAND-law enforcement will have jurisdiction SECONDARY DEVICES- booby traps, use of weapons, armed resistance and assault, secondary events
Locations where WMD are manufactured transported, stored, used, or disposed of are:
warehouses tank farms weapon depots hospitals labs truck terminals flight line areas maintenance facilities
Radioactive Containers
Type A: protective overpacks Type B: Casks
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